Chemistry is the branch of physical science is the study of
the composition, properties and behavior of matter. Chemistry is concerned with
atoms and their interactions with other atoms, and particularly with the
properties of chemical bonds. Chemistry is also concerned with the interactions
between atoms (or groups of atoms) and various forms of energy (e.g.
photochemical reactions, changes in phases of matter, separation of mixtures,
properties of polymers, etc.).
Chemistry is sometimes called "the central
science" because it connects physics with other natural sciences such as
geology and biology. Chemistry is a branch of physical science but distinct
from physics.
The etymology of the word chemistry has been much disputed.
The genesis of chemistry can be traced to certain practices, known as alchemy,
which had been practiced for several millennia in various parts of the world,
particularly the Middle East.
History
Ancient Egyptians pioneered the art of synthetic
"wet" chemistry up to 4,000 years ago. By 1000 BC ancient
civilizations were using technologies that formed the basis of the various
branches of chemistry such as; extracting metal from their ores, making pottery
and glazes, fermenting beer and wine, making pigments for cosmetics and
painting, extracting chemicals from plants for medicine and perfume, making
cheese, dying cloth, tanning leather, rendering fat into soap, making glass,
and making alloys like bronze.
Democritus' atomist philosophy was later adopted by Epicurus
(341–270 BCE).
The genesis of chemistry can be traced to the widely
observed phenomenon of burning that led to metallurgy—the art and science of
processing ores to get metals (e.g. metallurgy in ancient India). The greed for
gold led to the discovery of the process for its purification, even though the
underlying principles were not well understood—it was thought to be a
transformation rather than purification. Many scholars in those days thought it
reasonable to believe that there exist means for transforming cheaper (base) metals
into gold. This gave way to alchemy and the search for the Philosopher's Stone
which was believed to bring about such a transformation by mere touch.
Greek atomism dates back to 440 BC, as what might be
indicated by the book De Rerum Natura (The Nature of Things) written by the
Roman Lucretius in 50 BC. Much of the early development of purification methods
is described by Pliny the Elder in his Naturalis Historia.
A tentative outline is as follows:
Alchemy in Greco-Roman Egypt [ – 642 CE], the earliest
Western alchemists such as Mary the Jewess, Cleopatra the Alchemist, and
Zosimos of Panopolis described early laboratory equipment. They are estimated
to have lived between the first and third centuries.
Islamic alchemy [642 CE – 1200], the Muslim conquest of
Egypt; development of alchemy by Jābir ibn Hayyān, al-Razi and others; Jābir
modifies Aristotle's theories; advances in processes and apparatus.
European alchemy [1300 – present], Pseudo-Geber builds on
Arabic chemistry.[citation needed] From the 12th century, major advances in the
chemical arts shifted from Arab lands to western Europe.
Chemistry [1661], Boyle writes his classic chemistry text
The Sceptical Chymist.
Chemistry [1787], Lavoisier writes his classic Elements of
Chemistry.
Chemistry [1803], Dalton publishes his Atomic Theory.
Chemistry [1869], Dmitri Mendeleev presented his Periodic
table being the framework of the modern chemistry
The earliest pioneers of chemistry and the scientific
method, were medieval Arab and Persian scholars. They introduced precise
observation and controlled experimentation into the field and discovered numerous
chemical substances.
"Chemistry as a science was almost created by the
Muslims; for in this field, where the Greeks (so far as we know) were confined
to industrial experience and vague hypothesis, the Saracens introduced precise
observation, controlled experiment, and careful records. They invented and
named the alembic (al-anbiq), chemically analyzed innumerable substances,
composed lapidaries, distinguished alkalis and acids, investigated their
affinities, studied and manufactured hundreds of drugs. Alchemy, which the
Muslims inherited from Egypt, contributed to chemistry by a thousand incidental
discoveries, and by its method, which was the most scientific of all medieval
operations."
The most influential Muslim chemists were Jābir ibn Hayyān
(Geber, d. 815), al-Kindi (d. 873), al-Razi (d. 925), al-Biruni (d. 1048) and
Alhazen (d. 1039). Their works became more widely known in Europe in the
twelfth and thirteenth centuries, beginning with the Latin translation of
Jābir’s Kitab al-Kimya in 1144. The contribution of Indian alchemists and
metallurgists in the development of chemistry was also quite significant.
Antoine-Laurent de Lavoisier is considered the "Father
of Modern Chemistry".
For some practitioners alchemy was an intellectual pursuit,
and over time they got better at it. Paracelsus (1493–1541), for example,
rejected the 4-elemental theory, and with only a vague understanding of his
chemicals and medicines formed a hybrid of alchemy and science in what was to
be called iatrochemistry. Similarly, the influences of philosophers such as Sir
Francis Bacon (1561–1626) and René Descartes (1596–1650), who demanded more
rigor in mathematics and in removing bias from scientific observations, led to
a scientific revolution. In chemistry this began with Robert Boyle (1627–1691)
who came up with an equation known as Boyle's Law about the characteristics of
gaseous state.
Chemistry came of age when Antoine Lavoisier (1743–1794)
developed the theory of Conservation of mass in 1783; and the development of
the Atomic Theory by John Dalton around 1800. The Law of Conservation of Mass
resulted in the reformulation of chemistry based on this law[citation needed]
and the oxygen theory of combustion, which was largely based on the work of
Lavoisier. Lavoisier's fundamental contributions to chemistry were a result of
a conscious effort[citation needed] to fit all experiments into the framework
of a single theory.
Lavoisier established the consistent use of the chemical
balance, used oxygen to overthrow the phlogiston theory, and developed a new
system of chemical nomenclature and made contribution to the modern metric
system. Lavoisier also worked to translate the archaic and technical language
of chemistry into something that could be easily understood by the largely
uneducated masses, leading to an increased public interest in chemistry. All
these advances in chemistry led to what is usually called the chemical
revolution. The contributions of Lavoisier led to what is now called modern
chemistry—the chemistry that is studied in educational institutions all over
the world. It is because of these and other contributions that Antoine
Lavoisier is often celebrated as the "Father of Modern Chemistry".
The later discovery of Friedrich Wöhler that many natural substances, organic
compounds, can indeed be synthesized in a chemistry laboratory also helped the
modern chemistry to mature from its infancy.
The discovery of the chemical elements has a long history
from the days of alchemy and culminating in the creation of the periodic table
of the chemical elements by Dmitri Mendeleev (1834–1907) and later discoveries
of some synthetic elements.
Jöns Jacob Berzelius, Joseph Priestley, Humphry Davy, Linus
Pauling, Gilbert N. Lewis, Josiah Willard Gibbs, Robert Burns Woodward, and
Fritz Haber also made notable contributions.
The year 2011 was declared by the United Nations as the
International Year of Chemistry. It was an initiative of the International
Union of Pure and Applied Chemistry, and of the United Nations Educational,
Scientific, and Cultural Organization and involves chemical societies,
academics, and institutions worldwide and relied on individual initiatives to
organize local and regional activities.
Principles of Modern Chemistry
The current model of atomic structure is the quantum
mechanical model. Traditional chemistry starts with the study of elementary particles,
atoms, molecules, substances, metals, crystals and other aggregates of matter.
This matter can be studied in solid, liquid, or gas states, in isolation or in
combination. The interactions, reactions and transformations that are studied
in chemistry are usually the result of interactions between atoms, leading to
rearrangements of the chemical bonds which hold atoms together. Such behaviors
are studied in a chemistry laboratory.
The chemistry laboratory stereotypically uses various forms
of laboratory glassware, but glassware is not central to chemistry, and a great
deal of experimental (as well as applied/industrial chemistry) is done without
it.
A chemical reaction is a transformation of some substances
into one or more different substances. The basis of such a chemical
transformation is the rearrangement of electrons in the chemical bonds between
atoms. It can be symbolically depicted through a chemical equation, which
usually involves atoms as subjects. The number of atoms on the left and the
right in the equation for a chemical transformation is equal (when unequal, the
transformation by definition is not chemical, but rather a nuclear reaction or
radioactive decay). The type of chemical reactions a substance may undergo and
the energy changes that may accompany it are constrained by certain basic
rules, known as chemical laws.
Energy and entropy considerations are invariably important
in almost all chemical studies. Chemical substances are classified in terms of
their structure, phase, as well as their chemical compositions. They can be
analyzed using the tools of chemical analysis, e.g. spectroscopy and
chromatography. Scientists engaged in chemical research are known as chemists.
Most chemists specialize in one or more sub-disciplines. Several concepts are
essential for the study of chemistry; some of them are:
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